BioTeam, ICPEES/ECPM
- Doctorat en chimie des polymères
2013 - 2017
Sujet: "Développement de nouveaux polyesters par catalyse organométallique et enzymatique"
Directeur de thèse: Pr. Luc Avérous (responsable de l'équipe BioTeam à l'ICPEES)
Encadrant supplémentaire: Dr. Eric Pollet
Mon sujet de thèse s'inscrit dans le cadre du projet européen SYNPOL.
- Synthèse organique de polyesters biosourcés (catalyse organométallique et enzymatique), ingénierie macromoléculaire avec étude de la relation structure-propriété.
- Caractérisation structurale des polyesters synthétisés (FTIR, RMN (1H, 13C, 31P), CES)
- Analyses thermiques (DSC, ATG) et structure cristalline (DRX)
Publications scientifiques:
- ”Synthesis of potentially biobased copolyesters based on adipic acid and butanediols: kinetic study between 1,4- and 2,3-butanediol and their influence on crystallization and thermal properties”, Polymer, 2016, 99, 204-213.
- “Enzymatic synthesis of a biobased copolyester from poly(butylene succinate) and poly[(R)-3-hydroxybutyrate]: Study of reaction parameters on the transesterification rate”, Biomacromolecules, 2016, 17 (12), 4054–4063.
- “Synthesis and characterization of biobased poly(butylene succinate-ran-butylene adipate). Analysis of the composition-dependent physicochemical properties”, European Polymer Journal, 2017, 87, 84–98.
- “Tailoring the structure, morphology, and crystallization of isodimorphic poly(butylene succinate-ran-butylene adipate) random copolymers by changing composition and thermal history“, Macromolecules, 2017, 50 (2), 797-608, collaboration scientifique internationale.
- “Titanium-catalyzed transesterification as a route to the synthesis of fully biobased poly(3-hydroxybutyurate-co-butylene dicarboxylate) copolyesters, from their homopolyesters”, European Polymer Journal, (2017), 90, 92-104.
- “Synthesis and characterization of block poly(ester-ether-urethane)s from bacterial poly(3-hydroxybutyrate) oligomers”, Journal of Polymer Science, Part A: Polymer Chemistry, 2017, 55 (11), 1949-1961.
- “Enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters and characterization. Influence of 1,4- and 2,3-butanediol contents.”, European Polymer Journal, 2017, 97, 103-105.
- “Study on the structure-properties relationship of biodegradable and biobased aliphatic copolyesters based on 1,3-propanediol, 1,4-butanediol, succinic and adipic acids”, Polymer, 2017, 122, 105-116.
- “Synthesis and characterization of fully biobased poly(propylene succinate-ran-propylene adipate). Analysis of the architecture-dependent physicochemical behavior”, Journal of Polymer Science, Part A: Polymer Chemistry, 2017, DOI:10.1002/pola.28668.
Collaboration internationales:
- Dr. Parveen Sangwan (CSIRO, Victoria, Australie)
- Ricardo Pérez-Camargo et Dr. Alejandro Müller (POLYMAT, San Sebastian, Espagne)
Conférence internationale:
- 23rd Bio-Environmental Polymer Society (BEPS), 2015, Karlsruhe, Allemagne
